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If i start it, i get a black screen with nothing. Tried at last wine staging 2.12 in PlayOnLinux.
into Steam on linux and I was able to play and configure my steamcontroller in Big Picture mode.
It´s already added there.
Problem is, in native-steam is no big-picture-mode available, and in wined-steam clicking on "big picture mode" gives me a black-screen.
Apart from that: Try [this](https://www.codeweavers.com/compatibility/crossover/forum/steam?msg=194480), it's a solution for CrossOver but maybe it's the same on plain Wine.
But no, i did not really found a solution for that.